Mono(acetylacetonato)zirconium(IV) Aryloxides: Synthesis, Reactivity and Thermoanalytical Investigation

Autores

  • Raj Kaushal National Institute of Technology, Hamirpur, H.P. 177005
  • S S Bhatt Himachal Pradesh University, Summer Hill, Shimla, H.P. India 171005

Palavras-chave:

Zirconium, acetylacetone, chlorophenol, reactivity and thermal analysis

Resumo

A series of novel zirconium(IV) complexes, formulated as ZrCl3−n(acac)(OArI–V)n (where n =− 3; –OArI = OC6H4Cl-2, –OArII = OC6H4Cl-4, –OArIII = –OC6H3Cl2-2,4, OArIV = –OC6H3Cl2-2,6 and OArV = –OC6H2Cl3-2,4,6) were synthesized by reacting ZrCl3(acac) with corresponding substituted chlorophenols in separate experiments. The complexes were characterized by elemental analysis, molar conductance measurements, molecular weight determination, spectroscopic techniques (1HNMR and IR) and thermal gravimetric analysis. Based upon these studies, a triangular bipyramidal structure has been proposed. Acceptor properties of ZrCl3–n(acac)(OArI–V)n towards bidentate ligands such as 2,2’-bipyridyl and 1,10-phenanthroline allows the isolation of 1:1 addition compounds as shown by physicochemical, IR, and 1HNMR spectral studies. Keywords:Zirconium, acetylacetone, chlorophenol, reactivity and thermal analysis

Biografias do Autor

  • Raj Kaushal, National Institute of Technology, Hamirpur, H.P. 177005
    Deptt : chemistryRank: Assistant Professor
  • S S Bhatt, Himachal Pradesh University, Summer Hill, Shimla, H.P. India 171005
    deprtment of Chemistryrank : Professor

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Publicado

2012-04-12

Edição

Vol. 3 N.º 1 (2012)

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